| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Wilson Kajumula Masilingi | Ambassador | 2015 - 2021 |
| 2 | H.E. Liberata Mulamula | Ambassador | 2013 - 2015 |
| 3 | H.E. Mwanaidi Sinare Maajar | Ambassador | 2010 - 2013 |
| 4 | H.E. Ombeni Y. Sefue | Ambassador | 2007 - 2010 |
| 5 | H.E. Andrew Mhando Daraja | Ambassador | 2002 - 2007 |
| 6 | H.E. Mustafa Salim Nyang’anyi | Ambassador | 1995 - 2002 |
| 7 | H.E. Charles Musama Nyirabu | Ambassador | 1990 - 1995 |
| 8 | H.E. Asterius Magnus Hyera | Ambassador | 1984 - 1984 |
| 9 | H.E. Benjamin W. Mkapa | Ambassador | 1983 - 1984 |
| 10 | H.E. Paul L. Bomani | Ambassador | 1972 - 1983 |
| 11 | H.E. Gosbert Miarcell Rutabanzibwa | Ambassador | 1968 - 1972 |
| 12 | H.E. Chief Michael Lukumbuzya | Ambassador | 1965 - 1968 |
| 13 | H.E. Othman Shariff | Ambassador | 1964 - 1965 |
